Sequential, Kinetically Controlled Synthesis of Multicomponent Stereoisomeric Assemblies
نویسندگان
چکیده
منابع مشابه
Sequential, kinetically controlled synthesis of multicomponent stereoisomeric assemblies.
The reversibility of noncovalent and metal–ligand interactions has widely been exploited to synthesize a plethora of supramolecular and coordination-based assemblies under thermodynamic control. Occasionally, entrapment in local energy minima leads to the formation of metastable products, which are often converted into lower-energy products upon prolonged reaction times. In contrast, self-assem...
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The development of new practical and green methods for the synthesis of small heterocycles is an attractive area of research due to the well-known potential of heterocyclic small molecule scaffolds in the drug discovery process. Herein we report a one-pot, three-component sequential procedure for the synthesis of diversely 1,3,5- and 1,3,5,5-substituted hydantoins, in high yields and very mild ...
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Transfer printing by kinetically switchable adhesion to an elastomeric stamp shows promise as a powerful micromanufacturing method to pickup microstructures and microdevices from the donor substrate and to print them to the receiving substrate. This can be viewed as the competing fracture of two interfaces. This paper examines the mechanics of competing fracture in a model transfer printing sys...
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2012
ISSN: 0044-8249
DOI: 10.1002/ange.201108994